Electron Attachment Step in Electron Capture Dissociation (ECD) and Electron Transfer Dissociation (ETD)

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Electron attachment step in electron capture dissociation (ECD) and electron transfer dissociation (ETD).

We have made use of classical dynamics trajectory simultions and ab initio electronic structure calculations to estimate the cross sections with which electrons are attached (in electron capture dissociation (ECD)) or transferred (in electron transfer dissociation (ETD)) to a model system that contained both an S-S bond that is cleaved and a -NH(3)(+) positively charged site. We used a Landau-Z...

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ژورنال

عنوان ژورنال: The Journal of Physical Chemistry A

سال: 2005

ISSN: 1089-5639,1520-5215

DOI: 10.1021/jp050218d